“The great neuroscientist W. Gray Walter carried out a series of experiments in the late forties and fifties in which he used an electronic stroboscopic device in combination with EEG equipment to send rhythmic light flashes into the eyes of the subjects at frequencies ranging from ten to twenty five flashes per second. He was startled to find that the flickering seemed to alter the brain-wave activity of the whole cortex instead of just the areas associated with vision. Wrote Walter, “The rhythmic series of flashes appear to be breaking down some of the physiologic barriers between different regions of the brain. This means the stimulus of flicker received by the visual projection area of the cortex was breaking bounds— its ripples were overflowing into other areas.”
Now next point to make here is that many of the other promised benefits of brainwave entrainment stem from this basic foundation.  For example, it has been said that listening to brainwave entrainment resets the brain’s sodium/potassium ratio, greatly decreasing mental fatigue, and improving the transporting of positive neurochemicals between brain cells.  This promise rests on the fact that it has been shown that this occurs while one is in the theta state. Therefore, the answer would be that yes, because these audios do lead one’s brain into the theta state, then it follows that they would promote the resetting of the brain’s sodium potassium ratio.
The training process allows you to consciously access deeper levels of your brain and consciousness. Your whole brain power and function expands. You become intuitive, relaxed yet focused, creative, your thoughts become clearer and information processing improves more and more. The left and right brain hemisphere synchronizes and you'll start using the full power of your left (analitycal - logical - Intelligence) and right (creativity - imagination - visualisation) hemispheres together. To say that this helps in all imaginable areas of your life is an understatement. You'll also begin to discover deeper realities beyond the physical. You become happier, more relaxed and balanced.
Given that brainwaves control and connect such a vast range of human experience from thought to feelings to actions, it is easy to see how the deliberate control of brainwaves can affect mood, behaviors, motivation, and even physical health. Brainwave entrainment is a safe, simple, and scientifically proven method for quickly guiding the brain into a beneficial brainwave frequency to facilitate healthy sleep, lower stress, heal emotional problems, and improve physical health.
Entrainment is a term originally derived from complex systems theory, and denotes the way that two or more independent, autonomous oscillators with differing rhythms or frequencies, when situated in a context and at a proximity where they can interact for long enough, influence each other mutually, to a degree dependent on coupling force, such that they adjust until both oscillate with the same frequency. Examples include the mechanical entrainment or cyclic synchronization of two electric clothes dryers placed in close proximity, and the biological entrainment evident in the synchronized illumination of fireflies.[13]